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New Metal-Carbon Catalysts: I. Preparation Procedure and Application Area Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Translated
Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 1998, Volume: 39, Number: 3, Pages: 378-385 Pages count : 8
Authors Molchanov V.V. 1 , Chesnokov V.V. 1 , Buyanov R.A. 1 , Zaitseva N.A. 1
Affiliations
1 Boreskov Institute of Catalysis SB RAS

Abstract: New metal-filamentous carbon catalytic systems, which differ fundamentally from all known catalysts in structure and preparation procedure, are found. Metal-carbon catalysts are formed by decomposition of hydrocarbons over the iron-subgroup metals or their alloys. They contain metal particles anchored at the ends of the carbon filaments. By varying the conditions of hydrocarbon decomposition, one can impart desired properties to metal-carbon systems. These properties allow the use of the catalysts in complete and selective hydrogenation of unsaturated hydrocarbons and carboxylic acids, steam and CO2 methane conversion, CO methanation, Fischer-Tropsch synthesis, hydrodechlorination of chlorobenzene, dehydrogenation of n-butane, and CO oxidation. Depending on the carbon : metal ratio, the catalysts can be active in both complete and selective hydrogenation of dienes and alkynes. At high carbon : metal ratios, the selectivity to olefins is close to 100%.
Cite: Molchanov V.V. , Chesnokov V.V. , Buyanov R.A. , Zaitseva N.A.
New Metal-Carbon Catalysts: I. Preparation Procedure and Application Area
Kinetics and Catalysis. 1998. V.39. N3. P.378-385. publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
ArticleLinkType.TRANSLATED_TO_ORIGINAL: Молчанов В.В. , Чесноков В.В. , Буянов Р.А. , Зайцева Н.А.
Новые металл-углеродные катализаторы. I. Способ приготовления, область применения
Кинетика и катализ. 1998. Т.39. №3. С.407-415. publication_identifier_short.rinz_identifier_type
Dates:
Submitted: Oct 30, 1995
Accepted: Feb 12, 1997
Published print: May 1, 1998
Identifiers:
publication_identifier.wos_identifier_type WOS:000076097900013
publication_identifier.scopus_identifier_type 2-s2.0-0041391315
publication_identifier.rinz_identifier_type 13305234
publication_identifier.accession_number_identifier_type 1998:653495
publication_identifier.chemical_accession_number_identifier_type 129:236140