Mechanism of the Formation of Molybdenum Metallocarbene Complexes in the Gas Phase Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 2004, Volume: 45, Number: 4, Pages: 467-477 Pages count : 11 DOI: 10.1023/B:KICA.0000038072.50596.0d | ||
Tags | Oxide; Ethylene; Methane; Molybdenum | ||
Authors |
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Affiliations |
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Funding (2)
1 | International Science Foundation | RBG 000 |
2 | International Science Foundation | RBG 300 |
Abstract:
The reactions of Mo+ ions and MoxOy+ oxygen-containing molybdenum cluster ions (x = 1-3; y = 1-9) with methane, ethylene oxide, and cyclopropane were studied using ion cyclotron resonance. The formation of a number of organometallic ions, including the metallocarbene MoCH2+ , as well as molybdenum oxometallocarbenes MoxOyCH2+
(x = 1-3; y = 2, 4, 5, or 8) and MoxOy (CH4) ions (x = 1-3; y = 2, 5, or 8), was detected. The upper and lower limits of bond energies in oxometallocarbene complexes were evaluated: 111 > D0 (MoxOy+-CH2) > 82 kcal/mol (x = 1-3; y = 2, 5, 8).
Cite:
Goncharov V.B.
Mechanism of the Formation of Molybdenum Metallocarbene Complexes in the Gas Phase
Kinetics and Catalysis. 2004. V.45. N4. P.467-477. DOI: 10.1023/B:KICA.0000038072.50596.0d WOS Scopus РИНЦ
Mechanism of the Formation of Molybdenum Metallocarbene Complexes in the Gas Phase
Kinetics and Catalysis. 2004. V.45. N4. P.467-477. DOI: 10.1023/B:KICA.0000038072.50596.0d WOS Scopus РИНЦ
Original:
Гончаров В.Б.
Исследование механизма образования металлокарбеновых комплексов молибдена в газовой фазе
Кинетика и катализ. 2004. Т.45. №4. С.498-508. РИНЦ
Исследование механизма образования металлокарбеновых комплексов молибдена в газовой фазе
Кинетика и катализ. 2004. Т.45. №4. С.498-508. РИНЦ
Dates:
Submitted: | Nov 28, 2002 |
Published print: | Jul 1, 2004 |
Identifiers:
Web of science | WOS:000223776200002 |
Scopus | 2-s2.0-4344689092 |
Elibrary | 18243850 |
Chemical Abstracts | 2004:671539 |
Chemical Abstracts (print) | 142:74681 |
OpenAlex | W2094907596 |