The First Example of the Catalytic Activity of (μ-H)Os3(μ-OCNR1R2)(CO)10 Clusters in the Double Bond Migration Reactions of Allylic Systems Functionalised with an amido Group
, E-ISSN: 1364-551X
Ershova Victoriya A.
Tkachev Sergei V.
Golovin Anatoly V.
Al't Leonid Y.
Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation
As exemplified by the isomerisation of N-allylacetamide in the presence of hydridocarbonyl complexes (µ-H)Os3(µ-OCNR1R2)(CO)10 (R1 = H, Alk; R2 = Alk), it has been demonstrated for the first time that they are effective catalysts for the [1,2]-double bond shift under mild conditions in allylic compounds functionalised with an amido group.