Diene Condensation on Zeolites, II. Influence of the Zeolite Structure and the Nature of Substituting Cation on the Reaction of Alloocimene with α-Methacrolein Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 1997, Volume: 62, Number: 2, Pages: 287-291 Pages count : 5 DOI: 10.1007/BF02475465 | ||||
Tags | Alloocimene, Diene condensation, Zeolite © akadémiai kiadó, α-methacrolein | ||||
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Abstract:
The interaction of alloocimene with α-methacrolein on β-zeolite with various substituent cations (Fe, Ni, Zn, Cu and La) as well as on ZSM-5, erionite and mordenite has been studied at room temperature in dichloromethane. Substituent cations in β-zeolite as well as the silica/alumina ratio and alkali metal content in the zeolite structure were found to affect the formation of ocinal diastereomers. Therefore, we assume that a complex of active sites participates in the diene condensation: Alkali metals present in the zeolite suppress the (3+2)-cycloaddition reaction.
Cite:
Kuznetsova T.G.
, Ione K.G.
, Testova N.V.
, Salakhutdinov N.F.
Diene Condensation on Zeolites, II. Influence of the Zeolite Structure and the Nature of Substituting Cation on the Reaction of Alloocimene with α-Methacrolein
Reaction Kinetics and Catalysis Letters. 1997. V.62. N2. P.287-291. DOI: 10.1007/BF02475465 WOS Scopus РИНЦ
Diene Condensation on Zeolites, II. Influence of the Zeolite Structure and the Nature of Substituting Cation on the Reaction of Alloocimene with α-Methacrolein
Reaction Kinetics and Catalysis Letters. 1997. V.62. N2. P.287-291. DOI: 10.1007/BF02475465 WOS Scopus РИНЦ
Dates:
Submitted: | Aug 5, 1996 |
Accepted: | Nov 6, 1996 |
Published print: | Nov 1, 1997 |
Identifiers:
Web of science | WOS:000071752000013 |
Scopus | 2-s2.0-0008328263 |
Elibrary | 13268764 |
Chemical Abstracts | 1998:75811 |
Chemical Abstracts (print) | 128:192788 |
OpenAlex | W1975317215 |