In situ IR Spectroscopic Studies of HCOOH Decomposition over V-Ti-O Catalyst Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 2002, Volume: 76, Number: 1, Pages: 123-129 Pages count : 7 DOI: 10.1023/A:1015677730959 | ||
Tags | Formic acid, IR spectroscopy, Surface intermediate, V-Ti-O catalysts | ||
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Abstract:
Decomposition of formic acid over V-Ti-O catalysts was studied by in situ IR spectroscopy. Four surface compounds, among which are H-bonded acid, one mono- and two bidentate formates (BF1 and BF2), were identified in the temperature range of 100-190°C. The activation energy and rate of the BF2 decomposition were found equal to those for the CO formation. This equality points to the involvement of BF2 in the HCOOH decomposition into carbon monoxide.
Cite:
Popova G.Y.
, Chesalov Y.A.
, Andrushkevich T.V.
, Stoyanov E.S.
In situ IR Spectroscopic Studies of HCOOH Decomposition over V-Ti-O Catalyst
Reaction Kinetics and Catalysis Letters. 2002. V.76. N1. P.123-129. DOI: 10.1023/A:1015677730959 WOS Scopus РИНЦ
In situ IR Spectroscopic Studies of HCOOH Decomposition over V-Ti-O Catalyst
Reaction Kinetics and Catalysis Letters. 2002. V.76. N1. P.123-129. DOI: 10.1023/A:1015677730959 WOS Scopus РИНЦ
Dates:
Submitted: | Feb 7, 2002 |
Accepted: | Feb 20, 2002 |
Published print: | May 1, 2002 |
Identifiers:
Web of science | WOS:000176049900016 |
Scopus | 2-s2.0-0036015862 |
Elibrary | 13409978 |
Chemical Abstracts | 2002:479140 |
Chemical Abstracts (print) | 137:20112 |
OpenAlex | W164712527 |