Unusual Case of Catalysis by Palladium Clusters ArticleGenre_short.SHORT_COMMUNICATION
Journal |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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Output data | Year: 2005, Volume: 54, Number: 3, Pages: 803-806 Pages count : 4 DOI: 10.1007/s11172-005-0324-2 | ||||
Tags | α,α′-dialkylbenzyl alcohol, α-alkylbenzyl alcohol, Benzyl alcohol, Catalysis, Clusters, Dibenzyl ethers, Palladium | ||||
Authors |
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Affiliations |
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Funding (3)
1 | Russian Foundation for Basic Research | 05-03-32683 |
2 | Council for Grants of the President of the Russian Federation | НШ-1764.2003.03 |
3 | Президиум РАН |
Abstract:
An unusual for Pd catalysts dehydration of α-alkyl and α, α′-dialkylbenzyl alcohols PhCR′R″OH (R′ = H, Me, Et, Bu; R″ = H, Me) occurs in the presence of the palladium(I) cluster [Pd4(CO)4(OAc)4] (1) in an inert atmosphere to form ethers PhCR′R″-O-CR′ R″ and water. The catalyst is an intermediate of cluster 1 reduction to Pd black, while neither the starting cluster 1, nor Pd black, which is the decomposition product, are active in the catalysis of this reaction.
Cite:
Stolyarov I.P.
, Dobrokhotova Z.V.
, Kryukova G.N.
, Kozitsyna N.Y.
, Gekhman A.E.
, Vargaftik M.N.
, Moiseev I.I.
Unusual Case of Catalysis by Palladium Clusters
Russian Chemical Bulletin. 2005. V.54. N3. P.803-806. DOI: 10.1007/s11172-005-0324-2 WOS Scopus РИНЦ
Unusual Case of Catalysis by Palladium Clusters
Russian Chemical Bulletin. 2005. V.54. N3. P.803-806. DOI: 10.1007/s11172-005-0324-2 WOS Scopus РИНЦ
Original:
Столяров И.П.
, Доброхотова Ж.В.
, Крюкова Г.Н.
, Козицына Н.Ю.
, Гехман А.Е.
, Варгафтик М.Н.
, Моисеев И.И.
Необычный пример катализа кластерами палладия
Известия Академии наук. Серия химическая. 2005. №3. С.788-792. РИНЦ
Необычный пример катализа кластерами палладия
Известия Академии наук. Серия химическая. 2005. №3. С.788-792. РИНЦ
Dates:
Submitted: | Jan 12, 2005 |
Published print: | Mar 1, 2005 |
Identifiers:
Web of science | WOS:000232042300041 |
Scopus | 2-s2.0-25144499146 |
Elibrary | 13483180 |
Chemical Abstracts | 2005:1010035 |
Chemical Abstracts (print) | 144:488360 |
OpenAlex | W2952928760 |