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Catalytic Oxidation of Olefins and Alcohols with Hydrogen Peroxide in a Two-Phase System Giving Mono- and Dicarboxylic Acids Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Translated
Journal Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171
Output data Year: 2005, Volume: 54, Number: 8, Pages: 1847-1854 Pages count : 8 DOI: 10.1007/s11172-006-0047-z
Tags Alcohols, Carboxylic acids, Cycloalkenes, Oxidation, Peroxopolyoxotungstates, Phase-transfer catalysis, Unsaturated fatty acids
Authors Pai Z.P. 1 , Tolstikov A.G. 1 , Berdnikova P.V. 1 , Kustova G.N. 1 , Khlebnikova T.B. 1 , Selivanova N.V. 1 , Shangina A.B. 1 , Kostrovskii V.G. 1
Affiliations
1 Boreskov Institute of Catalysis SB RAS

Funding (2)

1 Russian Foundation for Basic Research 04-03-32425
2 The Ministry of Education and Science of the Russian Federation 41.015.1.1.2455

Abstract: The present study considered the influence of various factors on the catalytic activity of systems based on a combination of tetrakis(oxodiperoxotungsto)phosphate(3−) with quaternary ammonium cations, for example, with methyltri-n-octylammonium [Me(n-C8H17)3N]+. The catalysts were tested in oxidation of cycloolefins (cyclohexene and cyclooctene), alcohols (octan-1-ol and phenylmethanol), and unsaturated fatty acids (cis-9-octadecenoic and 12-hydroxy-9Z-octadecenoic acids) with a 30% hydrogen peroxide solution. These reactions proceed under mild conditions (atmospheric pressure, 80–90 °C) to give carboxylic acids. The catalytic systems were characterized by vibrational (IR and Raman) spectroscopy. The state of the systems formed from various precursors, viz., polyoxometallates and phase-transfer catalysts, was studied. It was demonstrated for the first time that the structure formation of peroxo complexes depends on the nature of the halide anion of the quaternary ammonium salt used. The melting points of individual catalytic complexes were determined. The optimal conditions for oxidation were found.
Cite: Pai Z.P. , Tolstikov A.G. , Berdnikova P.V. , Kustova G.N. , Khlebnikova T.B. , Selivanova N.V. , Shangina A.B. , Kostrovskii V.G.
Catalytic Oxidation of Olefins and Alcohols with Hydrogen Peroxide in a Two-Phase System Giving Mono- and Dicarboxylic Acids
Russian Chemical Bulletin. 2005. V.54. N8. P.1847-1854. DOI: 10.1007/s11172-006-0047-z publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
ArticleLinkType.TRANSLATED_TO_ORIGINAL: Пай З.П. , Толстиков А.Г. , Бердникова П.В. , Кустова Г.Н. , Хлебникова Т.Б. , Селиванова Н.В. , Шангина А.Б. , Костровский В.Г.
Каталитическое окисление олефиновых соединений и спиртов пероксидом водорода до моно- и дикарбоновых кислот
Известия Академии наук. Серия химическая. 2005. Т.54. №8. С.1794-1801. publication_identifier_short.rinz_identifier_type
Dates:
Submitted: Sep 5, 2003
Published print: Aug 1, 2005
Identifiers:
publication_identifier.wos_identifier_type WOS:000235326900014
publication_identifier.scopus_identifier_type 2-s2.0-31944452275
publication_identifier.rinz_identifier_type 13501660
publication_identifier.accession_number_identifier_type 2006:94194
publication_identifier.chemical_accession_number_identifier_type 145:438096
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