Synthesis of the Scalemic Form of Alkaloid (-)-Dipthocarpamine
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Translated
|
| Journal |
Russian Chemical Bulletin
ISSN: 1066-5285
, E-ISSN: 1573-9171
|
| Output data |
Year: 2000,
Volume: 49,
Number: 3,
Pages: 569-570
Pages count
: 2
DOI:
10.1007/BF02494796
|
| Tags |
(-)-dipthocarpamirie, Alkaloids, Asymmetric oxidation, Chiral complexes, Dialkyl sulfide |
| Authors |
Karpyshev N.N.
1
,
Tolstikov A.G.
1
,
Tolstikova O.V.
1
,
Yakovleva O.D.
1
,
Shmakov V.S.
2
|
| Affiliations |
| 1 |
Boreskov Institute of Catalysis SB RAS
|
| 2 |
Institute of Organic Chemistry, Ufa Scientific Centre of RAS, Russia
|
|
The scalemic form of active alkaloid (−)-dipthocarpamine was synthesized by asymmetric oxidation ofN-isopropyl-N′-(methylthiohexyl)urea with hydrogen peroxide in the presence of vanadium(IV) complexes with chiral Shiff's bases.