Oxidation of Cyclohexene and α-Pinene with O2-H 2 Mixture in the Presence of Supported Platinum or Palladium Catalysts
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Translated
|
| Journal |
Russian Chemical Bulletin
ISSN: 1066-5285
, E-ISSN: 1573-9171
|
| Output data |
Year: 2003,
Volume: 52,
Number: 7,
Pages: 1544-1551
Pages count
: 8
DOI:
10.1023/A:1025688908667
|
| Tags |
α-pinene, Catalysis, Cyclohexene, Heteropoly compounds, Hydrogen, Oxidation, Oxygen, Palladium, Platinum |
| Authors |
Kuznetsova N.I.
1
,
Kuznetsova L.I.
1
,
Kirillova N.V.
1
,
Pokrovskii L.M.
2
,
Detusheva L.G.
1
,
Ancel J.-E.
3
,
Likholobov V.A.
1
|
| Affiliations |
| 1 |
G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Akad. Lavrent´eva, 630090 Novosibirsk, Russian Federation
|
| 2 |
N. N. Vorozhtsov Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent´eva, 630090 Novosibirsk, Russian Federation
|
| 3 |
ARCHEMIS, 24 Jean Jaurès av., 69153 Decines Charpieu, Cédex, France
|
|
Funding (1)
|
1
|
Russian Foundation for Basic Research
|
00-15-97447
|
Oxidation of cyclohexene and α-pinene with an O2—H2 mixture in the catalytic systems containing Pt or Pd and heteropoly compounds (HPC) was studied. The main oxidation products are epoxides, allyl alcohols, and ketones. The highest yield of the oxidation products was obtained in the presence of the platinum catalyst in combination with HPC PW11 or PW11Fe. The reaction mechanism was proposed. A relationship between the HPC composition and the nature of intermediates involved in oxidation was examined.