Selective Aerobic Epoxidation of Olefins over NaY and NaZSM-5 Zeolites Containing Transition Metal Ions Full article
Conference |
4th International Symposium on Heterogeneous Catalysis and Fine Chemicals 08-12 Sep 1996 , Basel |
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Source | Heterogeneous Catalysis and Fine Chemicals IV : Proceedings of the 4th International Symposium on Heterogeneous Catalysis and Fine Chemicals, 8-12 September 1996, Basel, Switzerland Compilation, 1997. 675 c. ISBN 9780444823908. |
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Journal |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
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Output data | Year: 1997, Volume: 108, Pages: 337-344 Pages count : 8 DOI: 10.1016/S0167-2991(97)80922-6 | ||||
Tags | MOLECULAR-OXYGEN; ALDEHYDE; COMPLEXES; CATALYSTS; PW11COO395; COREDUCER | ||||
Authors |
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Affiliations |
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Funding (1)
1 | Russian Foundation for Basic Research | 96-03-34215 |
Abstract:
Aerobic epoxidation of different alkenes, including a number of natural terpenes, efficiently occurs under mild reaction conditions in the presence of isobutyraldehyde as a reductant and MNaY and MNaZSM-5 type zeolites (M=Co(II), Cu(II), Ni(II) and Fe(III)) as catalysts. Yields of the epoxidation products vary from 80 up to 99% depending on the olefin and catalyst. The reaction proceeds via chain radical mechanism, acylperoxy radicals being the main epoxidizing species.
Cite:
Kholdeeva O.A.
, Tkachev A.V.
, Romannikov V.N.
, Khavrutskii I.V.
, Zamaraev K.I.
Selective Aerobic Epoxidation of Olefins over NaY and NaZSM-5 Zeolites Containing Transition Metal Ions
In compilation Heterogeneous Catalysis and Fine Chemicals IV : Proceedings of the 4th International Symposium on Heterogeneous Catalysis and Fine Chemicals, 8-12 September 1996, Basel, Switzerland. 1997. – C.337-344. – ISBN 9780444823908. DOI: 10.1016/S0167-2991(97)80922-6 WOS Scopus РИНЦ
Selective Aerobic Epoxidation of Olefins over NaY and NaZSM-5 Zeolites Containing Transition Metal Ions
In compilation Heterogeneous Catalysis and Fine Chemicals IV : Proceedings of the 4th International Symposium on Heterogeneous Catalysis and Fine Chemicals, 8-12 September 1996, Basel, Switzerland. 1997. – C.337-344. – ISBN 9780444823908. DOI: 10.1016/S0167-2991(97)80922-6 WOS Scopus РИНЦ
Dates:
Published print: | Jan 1, 1997 |
Published online: | Sep 2, 2007 |
Identifiers:
Web of science | WOS:000071440500041 |
Scopus | 2-s2.0-3442892865 |
Elibrary | 15055897 |
Chemical Abstracts | 1998:375153 |
Chemical Abstracts (print) | 129:135810 |
OpenAlex | W1591706396 |