On the Mechanism of Olefin Polymerization by Ziegler-Natta Catalysts Review
Source | Industrial Developments Compilation, Springer. Berlin, Heidelberg.1983. 228 c. ISBN 9783540121893. |
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Journal |
Advances in Polymer Science
ISSN: 0065-3195 |
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Output data | Year: 1983, Volume: 51, Pages: 61-100 Pages count : 40 DOI: 10.1007/BFb0017585 | ||
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Abstract:
Novel data on the composition of active centers of Ziegler-Natta catalysts and on the mechanism of propagation and chain transfer reactions are reviewed. These data are derived from the following trends in the study of the mechanism of catalytic polymerization: a) determination of the number of active centers (mainly with the use of radioactive CO as a tag); b) analysis of the microstructure of polymers with the use of 13C-NMR; c) analysis of specific features of highly active supported catalysts; d) quantum-chemical calculation of the electronic structure of active centers and their reactions.
Cite:
Zakharov V.A.
, Bukatov G.D.
, Yermakov Y.I.
On the Mechanism of Olefin Polymerization by Ziegler-Natta Catalysts
In compilation Industrial Developments. – Springer., 1983. – C.61-100. – ISBN 9783540121893. DOI: 10.1007/BFb0017585 WOS РИНЦ
On the Mechanism of Olefin Polymerization by Ziegler-Natta Catalysts
In compilation Industrial Developments. – Springer., 1983. – C.61-100. – ISBN 9783540121893. DOI: 10.1007/BFb0017585 WOS РИНЦ
Dates:
Submitted: | Oct 1, 1982 |
Published online: | Jun 10, 2005 |
Identifiers:
Web of science | WOS:A1983RG15600002 |
Elibrary | 22693442 |
Chemical Abstracts | 1983:576290 |
Chemical Abstracts (print) | 99:176290 |
OpenAlex | W149080949 |