Sulphide Catalysts on Silica as a Support: VII. Isotope Exchange of Hydrogen Sulphide with Sulphide Catalysts Full article
Journal |
Applied Catalysis (up to 1991)
ISSN: 0166-9834 |
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Output data | Year: 1988, Volume: 45, Number: 2, Pages: 183-190 Pages count : 8 DOI: 10.1016/S0166-9834(00)83028-6 | ||
Tags | Chemical Reactions--Hydrogenation; Ion Exchange; Radioactive Materials--Tracers; Sulfur--Isotopes | ||
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Abstract:
Isotope exchange of H235S with the surface of sulphide catalysts Mo/SiO2 and (Ni-M)/SiO2 (M = Mo, W), prepared both by synthesis of surface metal complexes and by traditional impregnation, was studied. The rate of heteroexchange over the temperature range 150 to 300°C was shown to be almost the same on mono- and bimetallic sulphide catalysts obtained by the above procedure. The rate of thiophene hydrogenolysis increased with decreasing reactivity of surface sulphide groups towards the H235S heteroexchange.
Cite:
Startsev A.N.
, Artamonov E.V.
, Yermakov Y.I.
Sulphide Catalysts on Silica as a Support: VII. Isotope Exchange of Hydrogen Sulphide with Sulphide Catalysts
Applied Catalysis (up to 1991). 1988. V.45. N2. P.183-190. DOI: 10.1016/S0166-9834(00)83028-6 WOS Scopus РИНЦ
Sulphide Catalysts on Silica as a Support: VII. Isotope Exchange of Hydrogen Sulphide with Sulphide Catalysts
Applied Catalysis (up to 1991). 1988. V.45. N2. P.183-190. DOI: 10.1016/S0166-9834(00)83028-6 WOS Scopus РИНЦ
Dates:
Submitted: | Dec 23, 1987 |
Published print: | Dec 15, 1988 |
Published online: | Oct 2, 2001 |
Identifiers:
Web of science | WOS:A1988R732800002 |
Scopus | 2-s2.0-0024136250 |
Elibrary | 30936084 |
Chemical Abstracts | 1989:102499 |
Chemical Abstracts (print) | 110:102499 |
OpenAlex | W1581287433 |