Mechanism of Oxidation of Slightly Reduced 12-molybdovanadophosphate Blues with Oxygen in Solution Full article
Journal |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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Output data | Year: 1983, Volume: 32, Number: 4, Pages: 655-659 Pages count : 5 DOI: 10.1007/BF00953451 | ||
Tags | Oxidation; Oxygen; Hydrogen; Hydrogen Peroxide | ||
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Abstract:
Conclusions
1. Data on the thermodynamics of the oxidation of 12-molybdovanadophosphate blues by oxygen indicate a low probability for one-electron transfer in the reaction of the blue with oxygen and are consistent with the transfer of two, three, or four electrons.
2. Data on the kinetics of the oxidation of the blues by hydrogen peroxide and oxygen confirm the previously proposed mechanism for the oxidation of weakly reduced blues by oxygen, including the transfer of three electrons in the complex of O2 with the blue.
Cite:
Kozhevnikov I.V.
Mechanism of Oxidation of Slightly Reduced 12-molybdovanadophosphate Blues with Oxygen in Solution
Russian Chemical Bulletin. 1983. V.32. N4. P.655-659. DOI: 10.1007/BF00953451 WOS Scopus РИНЦ
Mechanism of Oxidation of Slightly Reduced 12-molybdovanadophosphate Blues with Oxygen in Solution
Russian Chemical Bulletin. 1983. V.32. N4. P.655-659. DOI: 10.1007/BF00953451 WOS Scopus РИНЦ
Original:
Кожевников И.В.
Механизм окисления слабо восстановленных синей 12-молибдованадофосфатов кислородом в растворе
Известия Академии наук. Серия химическая. 1983. №4. С.721-726. РИНЦ
Механизм окисления слабо восстановленных синей 12-молибдованадофосфатов кислородом в растворе
Известия Академии наук. Серия химическая. 1983. №4. С.721-726. РИНЦ
Dates:
Submitted: | Jul 5, 1982 |
Published print: | Apr 1, 1983 |
Identifiers:
Web of science | WOS:A1983RT15800004 |
Scopus | 2-s2.0-34250147425 |
Elibrary | 30904073 |
OpenAlex | W2065919986 |