Rate of Electrophilic Addition of Acetic Acid to 1-Hexene when Catalyzed by Heteropoly Acids ArticleGenre_short.SHORT_COMMUNICATION
Journal |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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Output data | Year: 1982, Volume: 31, Number: 7, Pages: 1470-1472 Pages count : 3 DOI: 10.1007/BF00954182 | ||
Tags | Acetic; Acetic Acid; Catalytic Activity; H2SO4; Dissociation Constant | ||
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Abstract:
Conclusions
1. The catalytic activity of heteropoly acids (HPA) in the reaction for the electrophilic addition of AcOH to 1-hexene is slightly dependent on the composition of the HPA and substantially exceeds the activity of H2SO4. The catalytic activity correlates with the dissociation constants of the acids.
2. The activity of the W HPA is higher than that of the Mo HPA due to the reduction of the Mo HPA during reaction, which leads to a decrease in their dissociation constants.
Cite:
Kulikov S.M.
, Kozhevnikov I.V.
Rate of Electrophilic Addition of Acetic Acid to 1-Hexene when Catalyzed by Heteropoly Acids
Russian Chemical Bulletin. 1982. V.31. N7. P.1470-1472. DOI: 10.1007/BF00954182 WOS Scopus РИНЦ
Rate of Electrophilic Addition of Acetic Acid to 1-Hexene when Catalyzed by Heteropoly Acids
Russian Chemical Bulletin. 1982. V.31. N7. P.1470-1472. DOI: 10.1007/BF00954182 WOS Scopus РИНЦ
Original:
Куликов С.М.
, Кожевников И.В.
Кинетика катализируемого гетерополикислотами электрофильного присоединения уксусной кислоты к гексену-1
Известия Академии наук. Серия химическая. 1982. №7. С.1651-1654. РИНЦ
Кинетика катализируемого гетерополикислотами электрофильного присоединения уксусной кислоты к гексену-1
Известия Академии наук. Серия химическая. 1982. №7. С.1651-1654. РИНЦ
Dates:
Submitted: | Dec 15, 1981 |
Published print: | Jul 1, 1982 |
Identifiers:
Web of science | WOS:A1982QB32600026 |
Scopus | 2-s2.0-34250234993 |
Elibrary | 30982021 |
OpenAlex | W1974255538 |
Citing:
DB | Citing |
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Web of science | 0 |