Study of the State of Heteropolyanions of Mo(Vl) and W(VI) with Aluminum (III) and Gallium (III) in Aqueous Solutions by the NMR Method Using 27Al, 71Ga, and Other Nuclei Full article
Journal |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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Output data | Year: 1988, Volume: 37, Number: 9, Pages: 1789-1792 Pages count : 4 DOI: 10.1007/BF00962489 | ||||
Tags | Aluminum; Aqueous Solution; Gallium; Heteropoly Compound | ||||
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Abstract:
Conclusions
1. From the 17O, 27Al, 71Ga, and 183W NMR spectra, we have established that the structure of heteropolyanions of dissolved heteropoly compounds K3[Al(OH)6;Mo6O18], K3[Ga(OH)6Mo6O18] and H5[GaW12O40] is retained in aqueous solutions.
2. The 27Al(71Ga) NMR spectra are sufficiently characteristic for identification of anions of hexamolybdate and dodecatungstates of aluminum (gallium) in aqueous solutions.
Cite:
Fedotov M.A.
, Kazanskii L.P.
Study of the State of Heteropolyanions of Mo(Vl) and W(VI) with Aluminum (III) and Gallium (III) in Aqueous Solutions by the NMR Method Using 27Al, 71Ga, and Other Nuclei
Russian Chemical Bulletin. 1988. V.37. N9. P.1789-1792. DOI: 10.1007/BF00962489 WOS Scopus РИНЦ
Study of the State of Heteropolyanions of Mo(Vl) and W(VI) with Aluminum (III) and Gallium (III) in Aqueous Solutions by the NMR Method Using 27Al, 71Ga, and Other Nuclei
Russian Chemical Bulletin. 1988. V.37. N9. P.1789-1792. DOI: 10.1007/BF00962489 WOS Scopus РИНЦ
Original:
Федотов М.А.
, Казанский Л.П.
Изучение состояния гетерополианионов Mo (VI) и W (VI) с алюминием (III) и галлием (III) в водных растворах методом ЯМР 27Al, 71Ga и других ядер
Известия Академии наук. Серия химическая. 1988. №9. С.2000-2003. РИНЦ
Изучение состояния гетерополианионов Mo (VI) и W (VI) с алюминием (III) и галлием (III) в водных растворах методом ЯМР 27Al, 71Ga и других ядер
Известия Академии наук. Серия химическая. 1988. №9. С.2000-2003. РИНЦ
Dates:
Submitted: | Mar 2, 1987 |
Published print: | Sep 1, 1988 |
Identifiers:
Web of science | WOS:A1988AD10500011 |
Scopus | 2-s2.0-2442741922 |
Elibrary | 31100519 |
OpenAlex | W2073852522 |