Acidoligand Substitution in Large Palladium Clusters Full article
Journal |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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Output data | Year: 1989, Volume: 38, Number: 4, Pages: 762-766 Pages count : 5 DOI: 10.1007/BF00953288 | ||||
Tags | Oxide; Acetate; Potassium; Aqueous Solution; Palladium | ||||
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Abstract:
Conclusions
1. In an aqueous solution of potassium hexafluorophosphate, the outer-sphere acetate anions in the large cluster with the idealized formula Pd561 Phen60(OAc)180 (Phen=1,10-phenanthroline) are completely replaced by outer-sphere hexafluorophosphate anions and coordinated oxide anions.
2. Upon substitution of the acetate ligands, the icosahedral packing of the palladium atoms in the metal framework of the large cluster is preserved, but the distance between atoms in the outer layer increases substantially.
Cite:
Zagorodnikov V.P.
, Vargaftik M.N.
, Kochubey D.I.
, Likholobov V.A.
, Kolomiichuk V.N.
, Naumochkin A.N.
, Chuvilin A.L.
, Novotortsev V.M.
, Ellert O.G.
, Moiseev I.I.
Acidoligand Substitution in Large Palladium Clusters
Russian Chemical Bulletin. 1989. V.38. N4. P.762-766. DOI: 10.1007/BF00953288 WOS Scopus РИНЦ
Acidoligand Substitution in Large Palladium Clusters
Russian Chemical Bulletin. 1989. V.38. N4. P.762-766. DOI: 10.1007/BF00953288 WOS Scopus РИНЦ
Original:
Загородников В.П.
, Варгафтик М.Н.
, Кочубей Д.И.
, Лихолобов В.А.
, Коломийчук В.Н.
, Наумочкин А.Н.
, Чувилин А.Л.
, Новоторцев В.М.
, Эллерт О.Г.
, Моисеев И.И.
Замещение ацидолиганда в гигантском кластере палладия
Известия Академии наук. Серия химическая. 1989. №4. С.849-854. РИНЦ
Замещение ацидолиганда в гигантском кластере палладия
Известия Академии наук. Серия химическая. 1989. №4. С.849-854. РИНЦ
Dates:
Submitted: | Dec 9, 1987 |
Published print: | Apr 1, 1989 |
Identifiers:
Web of science | WOS:A1989CN03200021 |
Scopus | 2-s2.0-34249973583 |
Elibrary | 30988429 |
OpenAlex | W2022137147 |