HREELS/TDS Study of NO Reaction with Hydrogen on Pt(100) Surface
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Journal |
Catalysis Letters
ISSN: 1011-372X
, E-ISSN: 1572-879X
|
| Output data |
Year: 1994,
Volume: 28,
Number: 2-4,
Pages: 153-160
Pages count
: 8
DOI:
10.1007/BF00806044
|
| Tags |
autocatalysis, NO + H2 reaction, platinum, surface reconstruction |
| Authors |
Zemlyanov D.Yu.
1
,
Smirnov M.Yu.
1
,
Gorodetskii V.V.
1
|
| Affiliations |
| 1 |
Boreskov Institute of Catalysis, Novosibirsk 630090, Russia
|
|
Funding (2)
|
1
|
Russian Foundation for Basic Research
|
93-03-4793
|
|
2
|
International Science Foundation
|
Ch3-6754-0935
|
NO adsorption on a Pt(100)-(hex) surface and NOads reaction with hydrogen at 300 K have been studied by HREELS, LEED, TDS and isothermal desorption. NO adsorbs in molecular form, its molecules gathering in islands with a high local coverage. Surface reconstruction into a (1 × 1) phase proceeds within the boundaries of islands. Reaction NO + H2 is performed via NOads previous heating in vacuum at Th = 375–425 K. Kinetics of NOads titration appears to be autocatalytic. Nitrogen is the major reaction product.