Study of the Mechanism of Ethylene Oxidation by Palladium(II) Complexes Containing Nitro and/or Nitrato Ligands in Chloroform
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Journal |
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic)
ISSN: 0304-5102
|
| Output data |
Year: 1989,
Volume: 50,
Number: 2,
Pages: 167-179
Pages count
: 13
DOI:
10.1016/0304-5102(89)85060-6
|
| Authors |
Beck I.E.
1
,
Gusevskaya E.V.
1
,
Stepanov A.G.
1
,
Likholobov V.A.
1
,
Nekipelov V.M.
1
,
Yermakov Y.I.
1
,
Zamaraev K.I.
1
|
| Affiliations |
|
Complexes of Pd(NOn)2−mClmL2 (where n = 2, 3; m = 0,1, 2; L= CH3CN, CD3CN) were synthesized and their reactivities towards ethylene and propylene oxidation in a chloroform medium were investigated. The detailed mechanism of ethylene oxidation by dinitro- and mono-nitrato complexes of palladium in chloroform solutions was studied by IR and 1H NMR spectroscopy. The structures and routes of decomposition of the intermediates to reaction end products are proposed.