Supported Nickel Catalysts for Ethylene Oligomerization Full article
Journal |
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic)
ISSN: 0304-5102 |
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Output data | Year: 1991, Volume: 69, Number: 1, Pages: 129-136 Pages count : 8 DOI: 10.1016/0304-5102(91)80109-G | ||||
Tags | Catalysis; Ethylene - Polymerization; Polymerization - Catalysts | ||||
Authors |
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Abstract:
New supported nickel catalysts for ethylene oligomerization have been obtained by the reaction of the nickel complex (I) with functional groups of modified silica (or alumina) or with magnesium hydride. Silica and alumina were modified by treatment with Al(CH3)3 or with Ti(CH2-C6H5)4. A number of the synthesized catalysts exhibit high activity and high selectivity in ethylene oligomerization. At high temperature (above 90 °C) some catalysts produced a mixture of linear α-olefins and polymer. Experimental data on the interaction of the Ni complex I with the different supports and the composition of the surface Ni complexes are reported.
Cite:
Nesterov G.A.
, Zakharov V.A.
, Fink G.
, Fenzl W.
Supported Nickel Catalysts for Ethylene Oligomerization
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic). 1991. V.69. N1. P.129-136. DOI: 10.1016/0304-5102(91)80109-G WOS Scopus РИНЦ
Supported Nickel Catalysts for Ethylene Oligomerization
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic). 1991. V.69. N1. P.129-136. DOI: 10.1016/0304-5102(91)80109-G WOS Scopus РИНЦ
Dates:
Submitted: | Jan 21, 1991 |
Accepted: | May 24, 1991 |
Published print: | Oct 1, 1991 |
Published online: | Oct 2, 2001 |
Identifiers:
Web of science | WOS:A1991GJ05500011 |
Scopus | 2-s2.0-0026239504 |
Elibrary | 31152995 |
Chemical Abstracts | 1992:7009 |
Chemical Abstracts (print) | 116:7009 |
OpenAlex | W2082380965 |