Crystal Structure of a Platinum Carbonyl Phosphine Cluster Pt4(CO)5[P(C2H5)3]4 and the IR Bands of CO Groups with Different Coordination to the Metal atoms Full article
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Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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Output data | Year: 1985, Volume: 26, Number: 2, Pages: 216-224 Pages count : 9 DOI: 10.1007/BF00754227 | ||||
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Abstract:
The crystal structure of Pt4(CO)5(PEt3)4 was determined and the IR spectra of this compound in the VCO region characteristic for such clusters were studied. Four models for the interaction of CO with metals upon adsorption were proposed on the basis of the geometrical parameters obtained for the coordination of CO in this and other clusters. Calculation of the frequencies and shape of the vibrations of all four models showed that we must independently evaluate the force constants of the interaction of the CO groups with the remaining part of the complex in order to develop reliable spectral indicators for the specific type of CO coordination.
Cite:
Klevtsova R.F.
, Yurchenko E.N.
, Glinskaya L.A.
, Burgina E.B.
, Eremenko N.K.
, Bakakin V.V.
Crystal Structure of a Platinum Carbonyl Phosphine Cluster Pt4(CO)5[P(C2H5)3]4 and the IR Bands of CO Groups with Different Coordination to the Metal atoms
Journal of Structural Chemistry. 1985. V.26. N2. P.216-224. DOI: 10.1007/BF00754227 WOS Scopus РИНЦ
Crystal Structure of a Platinum Carbonyl Phosphine Cluster Pt4(CO)5[P(C2H5)3]4 and the IR Bands of CO Groups with Different Coordination to the Metal atoms
Journal of Structural Chemistry. 1985. V.26. N2. P.216-224. DOI: 10.1007/BF00754227 WOS Scopus РИНЦ
Original:
Клевцова Р.Ф.
, Юрченко Э.Н.
, Глинская Л.А.
, Бургина Е.Б.
, Еременко Н.К.
, Бакакин В.В.
Кристаллическая структура карбонилфосфинового кластера платины PPt4(CO)5[P(C2H5)3]4 и проблема ИК-спектрального проявления колебаний групп CO, различным образом координированных атомами металлов
Журнал структурной химии. 1985. Т.26. №2. С.84-93. РИНЦ
Кристаллическая структура карбонилфосфинового кластера платины PPt4(CO)5[P(C2H5)3]4 и проблема ИК-спектрального проявления колебаний групп CO, различным образом координированных атомами металлов
Журнал структурной химии. 1985. Т.26. №2. С.84-93. РИНЦ
Dates:
Submitted: | Apr 27, 1983 |
Published print: | Mar 1, 1985 |
Identifiers:
Web of science | WOS:A1985AXF8000013 |
Scopus | 2-s2.0-24644486780 |
Elibrary | 31109585 |
OpenAlex | W2036228423 |