Paramagnetic 183W N.M.R. Chemical Shifts in Heteropolytungstates Full article
Journal |
Journal of the Chemical Society, Chemical Communications (1972-1995, Chemical Communications 1996-Present)
ISSN: 0022-4936 |
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Output data | Year: 1983, Number: 8, Pages: 417-419 Pages count : 3 DOI: 10.1039/c39830000417 | ||||
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Abstract:
The intensity and position of the resonances in the 183W n.m.r. spectra of the paramagnetic Ce3+(PW11O39)211– and the diamagnetic Ce4+(PW11O39)210– complex anions, which have a different solid-state structure, indicate that they also have different structures in aqueous solution; a high degree of electron delocalization from Ce3+ to the four adjacent tungsten atoms is deduced from the significant 183W chemical shifts.
Cite:
Kazansky L.P.
, Fedotov M.A.
Paramagnetic 183W N.M.R. Chemical Shifts in Heteropolytungstates
Journal of the Chemical Society, Chemical Communications (1972-1995, Chemical Communications 1996-Present). 1983. N8. P.417-419. DOI: 10.1039/c39830000417 WOS Scopus РИНЦ
Paramagnetic 183W N.M.R. Chemical Shifts in Heteropolytungstates
Journal of the Chemical Society, Chemical Communications (1972-1995, Chemical Communications 1996-Present). 1983. N8. P.417-419. DOI: 10.1039/c39830000417 WOS Scopus РИНЦ
Dates:
Submitted: | Aug 27, 1982 |
Identifiers:
Web of science | WOS:A1983QL99300009 |
Scopus | 2-s2.0-33847274241 |
Elibrary | 28775326 |
Chemical Abstracts | 1983:481493 |
Chemical Abstracts (print) | 99:81493 |
OpenAlex | W1973978792 |