15N Nuclear Magnetic Resonance Studies of the NO-O2-NH3 Reaction over ZSM-5 Zeolites Full article
Journal |
Journal of the Chemical Society - Faraday Transactions (1990-1998, in 1999 become Physical Chemistry Chemical Physics)
ISSN: 0956-5000 |
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Output data | Year: 1992, Volume: 88, Number: 10, Pages: 1473-1476 Pages count : 4 DOI: 10.1039/FT9928801473 | ||
Tags | NITRIC-OXIDE | ||
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Abstract:
15 N nuclear magnetic resonance spectra produced by adsorption on ZSM-5 zeolites of NO alone or together with O2 and NH3 have been examined. N2 and N2O as products of NO disproportionation were identified by their 15N NMR spectra. Cationic and acidic centres were suggested to be responsible for the catalytic activity of zeolites in this reaction. The 14N–15N isotopic exchange between reaction components indicates the formation of the intermediate complexes between NH3 and NxOy· M+ species in the adsorbed state.
Cite:
Mastikhin V.M.
, Filimonova S.V.
15N Nuclear Magnetic Resonance Studies of the NO-O2-NH3 Reaction over ZSM-5 Zeolites
Journal of the Chemical Society - Faraday Transactions (1990-1998, in 1999 become Physical Chemistry Chemical Physics). 1992. V.88. N10. P.1473-1476. DOI: 10.1039/FT9928801473 WOS Scopus РИНЦ
15N Nuclear Magnetic Resonance Studies of the NO-O2-NH3 Reaction over ZSM-5 Zeolites
Journal of the Chemical Society - Faraday Transactions (1990-1998, in 1999 become Physical Chemistry Chemical Physics). 1992. V.88. N10. P.1473-1476. DOI: 10.1039/FT9928801473 WOS Scopus РИНЦ
Dates:
Submitted: | Jun 10, 1991 |
Published print: | May 21, 1992 |
Identifiers:
Web of science | WOS:A1992HV68800018 |
Scopus | 2-s2.0-0000290374 |
Elibrary | 28786313 |
Chemical Abstracts | 1992:413650 |
Chemical Abstracts (print) | 117:13650 |
OpenAlex | W1977016589 |