Synthesis and Catalytic Properties of Complexes of Transition-Metals with Ligands Attached to Surfaces of Oxide Supports. 6. Synthesis of Polynuclear Palladium Complexes with Phosphine-Ligands Attached to a Silica-Gel Surface Full article
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Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 1981, Volume: 22, Number: 4, Pages: 804-808 Pages count : 5 | ||
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Abstract:
The preparation of Pd polynuclear catalysts stabilized on SiO2 gel supports by complexation with phosphine-type ligands is described. The catalytic polynuclear complex has the formula R2PdnX2 (R = diphosphine attached to silica gel and X = a ligand). In this preparation R2Pd(OAc)2 is treated with formic acid in benzene and then with Pd(OAc)2 in benzene to given R2Pd2(OAc)2 and these steps can be repeated several times to give R2Pdn(OAc)2 (1 ≤ n ≤ 5). The spectra indicated the formation of Pd cluster compounds. The catalytic response increases as n increases.
Cite:
Semikolenov V.A.
, Likholobov V.A.
, Ermakov Y.I.
Synthesis and Catalytic Properties of Complexes of Transition-Metals with Ligands Attached to Surfaces of Oxide Supports. 6. Synthesis of Polynuclear Palladium Complexes with Phosphine-Ligands Attached to a Silica-Gel Surface
Kinetics and Catalysis. 1981. V.22. N4. P.804-808. WOS РИНЦ
Synthesis and Catalytic Properties of Complexes of Transition-Metals with Ligands Attached to Surfaces of Oxide Supports. 6. Synthesis of Polynuclear Palladium Complexes with Phosphine-Ligands Attached to a Silica-Gel Surface
Kinetics and Catalysis. 1981. V.22. N4. P.804-808. WOS РИНЦ
Original:
Семиколенов В.А.
, Лихолобов В.А.
, Ермаков Ю.И.
Синтез и каталитические свойства комплексов переходных металлов с лигандами, закрепленными на поверхности окисных носителей. VI. Синтез полиядерных комплексов палладия с закрепленными на поверхности силикагеля фосфиновыми лигандами
Кинетика и катализ. 1981. Т.22. №4. С.1026-1030. РИНЦ
Синтез и каталитические свойства комплексов переходных металлов с лигандами, закрепленными на поверхности окисных носителей. VI. Синтез полиядерных комплексов палладия с закрепленными на поверхности силикагеля фосфиновыми лигандами
Кинетика и катализ. 1981. Т.22. №4. С.1026-1030. РИНЦ
Identifiers:
Web of science | WOS:A1981NR45600015 |
Elibrary | 30633621 |
Citing:
DB | Citing |
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Web of science | 1 |