Mechanism of the Catalytic Reaction of Methanol with H2S Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
||
---|---|---|---|
Output data | Year: 1993, Volume: 34, Number: 5, Pages: 790-796 Pages count : 7 | ||
Tags | NUCLEAR | ||
Authors |
|
||
Affiliations |
|
Abstract:
Kinetic regularities of the reaction of methanol with H2S in the presence of Al2O3 and WO3/Al2O3 were studied using the flow-circulation method. Based on kinetic data and results obtained by high-resolution NMR, a mechanism is suggested. According to this mechanism, under the effect of CH3OH and CH3SH, the catalyst surface is methoxylated, and then CH3O groups react with H2S or another CH3SH molecule. Kinetic models of the reaction that occurs on the inhomogeneous surface of a catalyst are proposed.
Cite:
Mashkina A.V.
, Mastikhin V.M.
, Mashkin V.Y.
, Nosov A.V.
, Kudenkov V.M.
Mechanism of the Catalytic Reaction of Methanol with H2S
Kinetics and Catalysis. 1993. V.34. N5. P.790-796. WOS РИНЦ
Mechanism of the Catalytic Reaction of Methanol with H2S
Kinetics and Catalysis. 1993. V.34. N5. P.790-796. WOS РИНЦ
Original:
Машкина А.В.
, Мастихин В.М.
, Машкин В.Ю.
, Носов А.В.
, Куденков В.М.
Исследование механизма каталитической реакции метанола с H2S
Кинетика и катализ. 1993. Т.34. №5. С.880-886. РИНЦ
Исследование механизма каталитической реакции метанола с H2S
Кинетика и катализ. 1993. Т.34. №5. С.880-886. РИНЦ
Dates:
Submitted: | Jul 23, 1992 |
Identifiers:
Web of science | WOS:A1993MW17100027 |
Elibrary | 29283817 |