Alumina-Supported Sulfided Catalysts. V. Effect of P and F on the Catalytic Activity of Hydrodesulfurization Sulfided Catalysts Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
||
---|---|---|---|
Output data | Year: 1994, Volume: 35, Number: 4, Pages: 552-558 Pages count : 7 | ||
Tags | METAL-COMPLEX PRECURSORS; Co-Mo CATALYSTS; THIOPHENE HYDROGENOLYSIS; CUMENE CONVERSION; GAMMA-ALUMINA; PHOSPHORUS; SILICA; ADDITIVES; SURFACE; CARBON Addresses | ||
Authors |
|
||
Affiliations |
|
Abstract:
Phosphorus and fluorine additives incorporated into the Ni-Mo/Al2O3 sulfided catalysts on various stages of their preparation considerably lower the activation energy of the thiophene hydrogenolysis reaction. The interaction of promoting additives with the active component of the hydrodesulfurization catalysts is proved by XPS and P-31 NMR. The effect of additives is discussed in terms of a synchronous mechanism involving interaction of reacting molecules in the coordination sphere of a bimetallic sulfide compound.
Cite:
Startsev A.N.
, Klimov O.V.
, Kalinkin A.V.
, Mastikhin V.M.
Alumina-Supported Sulfided Catalysts. V. Effect of P and F on the Catalytic Activity of Hydrodesulfurization Sulfided Catalysts
Kinetics and Catalysis. 1994. V.35. N4. P.552-558. WOS РИНЦ
Alumina-Supported Sulfided Catalysts. V. Effect of P and F on the Catalytic Activity of Hydrodesulfurization Sulfided Catalysts
Kinetics and Catalysis. 1994. V.35. N4. P.552-558. WOS РИНЦ
Original:
Старцев А.Н.
, Климов О.В.
, Калинкин А.В.
, Мастихин В.М.
Нанесенные на Al2O3 сульфидные катализаторы. V. Влияние P и F на каталитическую активность сульфидных катализаторов гидрообессеривания
Кинетика и катализ. 1994. Т.35. №4. С.601-607. РИНЦ
Нанесенные на Al2O3 сульфидные катализаторы. V. Влияние P и F на каталитическую активность сульфидных катализаторов гидрообессеривания
Кинетика и катализ. 1994. Т.35. №4. С.601-607. РИНЦ
Dates:
Submitted: | Jun 30, 1993 |
Identifiers:
Web of science | WOS:A1994PG22800021 |
Elibrary | 29284339 |