SciAct
Toggle navigation
  • EN
  • RU

Sections:

  • Articles
  • Books
  • Conference attendances
  • Conference theses
  • Patents

Liquid-Phase Oxidation of Propylene on Supported Palladium Mono- and Bimetallic Catalysts in Acetic Acid Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Translated
Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 1991, Volume: 32, Number: 2 pt 1, Pages: 323-329 Pages count : 7
Tags Catalysts - Platinum Metals Catalysts - Supported Glycols - Synthesis Palladium and Alloys - Applications Rhodium and Alloys - Applications
Authors Karandin A.V. 1 , Gusevskaya E.V. 1 , Likholobov V.A. 1 , Boronin A.I. 1 , Moroz E.M. 1
Affiliations
1 Institute of Catalysis

Abstract: Oxidation of propylene into propylene glycol and its acetates in acetic acid solutions of nitric acid was investigated in the presence of heterogeneous palladium, palladium-platinum, and palladium-rhodium catalysts on different supports (carbon, silica gel, titanium dioxide). It was found that the reaction basically takes place with the participation of the solid catalyst, although partially and in solution due to washing of the active components from the support. Palladium-platinum catalysts have the highest resistance to deactivation by the reaction medium. XPS and XPA showed that the formation of cyanide complexes of the metals on the surface of the support is one of the causes of deactivation of the catalysts. The possibility of regenerating the catalysts was demonstrated.
Cite: Karandin A.V. , Gusevskaya E.V. , Likholobov V.A. , Boronin A.I. , Moroz E.M.
Liquid-Phase Oxidation of Propylene on Supported Palladium Mono- and Bimetallic Catalysts in Acetic Acid
Kinetics and Catalysis. 1991. V.32. N2 pt 1. P.323-329. publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
ArticleLinkType.TRANSLATED_TO_ORIGINAL: Карандин А.В. , Гусевская Е.В. , Лихолобов В.А. , Боронин А.И. , Мороз Э.М.
Жидкофазное окисление пропилена на нанесенных палладиевых моно- и биметаллических катализаторах в уксусной кислоте
Кинетика и катализ. 1991. Т.32. №2. С.367-374. publication_identifier_short.rinz_identifier_type
Dates:
Published print: Mar 1, 1991
Identifiers:
publication_identifier.wos_identifier_type WOS:A1991GK59100017
publication_identifier.scopus_identifier_type 2-s2.0-0026219107
publication_identifier.rinz_identifier_type 31169307