Mechanism of the Liquid-Phase Oxidation of Diethyl Sulfide Catalyzed by Heteropoly Acids
Full article
Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736
, E-ISSN: 1588-2837
|
Output data |
Year: 1982,
Volume: 21,
Number: 1-2,
Pages: 109-114
Pages count
: 6
DOI:
10.1007/BF02064782
|
Authors |
Tarabanko V.E.
1
,
Sidelnikov V.N.
1
,
Kozhevnikov I.V.
1
|
Affiliations |
1 |
Institute of Catalysis, Novosibirsk, USSR
|
|
It has been established that in the oxidation of diethyl sulfide by 18O2 in CH3C16O2H−H216O solution at 369 K catalyzed by heteropoly acids, sulfoxide and sulfone with 44–54%18O enrichment are formed. The process is accompanied by isotope exchange of molecular oxygen