Mossbauer Spectroscopy Studies on the Complex Formation of H2PtCl6 and SnCl2 in Acetone Solution Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 1983, Volume: 23, Number: 1-2, Pages: 113-117 Pages count : 5 DOI: 10.1007/BF02065674 | ||
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Abstract:
Complex formation of H2PtCI6 and SnCl2 in the presence of HCI in acetone has been studied quantitatively by using Mossbauer spectroscopy. It has been revealed that Pt(IV) is rapidly reduced by Sn(II) to Pt(II) and with time the product complex [PtCl2 (SnCI3)2]n- transforms into a compound with Pt : Sn -- 1 : 1 ratio that, in turn, transforms to metallic platinum and Sn(IV). In these conditions no formation of stable Pt(O) clusters was observed.
Cite:
Yurchenko E.N.
, Kuznetsov V.I.
Mossbauer Spectroscopy Studies on the Complex Formation of H2PtCl6 and SnCl2 in Acetone Solution
Reaction Kinetics and Catalysis Letters. 1983. V.23. N1-2. P.113-117. DOI: 10.1007/BF02065674 WOS Scopus РИНЦ
Mossbauer Spectroscopy Studies on the Complex Formation of H2PtCl6 and SnCl2 in Acetone Solution
Reaction Kinetics and Catalysis Letters. 1983. V.23. N1-2. P.113-117. DOI: 10.1007/BF02065674 WOS Scopus РИНЦ
Dates:
Submitted: | Nov 12, 1982 |
Accepted: | Jan 13, 1983 |
Published print: | Mar 1, 1983 |
Published online: | Aug 3, 2013 |
Identifiers:
Web of science | WOS:A1983SB83400022 |
Scopus | 2-s2.0-0348101539 |
Elibrary | 31176882 |
Chemical Abstracts | 1984:92075 |
Chemical Abstracts (print) | 100:92075 |
OpenAlex | W2164773342 |