Influence of the Basicity of Butyl Alcohols on Their Reactivity Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 1981, Volume: 16, Number: 4, Pages: 365-369 Pages count : 5 DOI: 10.1007/BF02066592 | ||
Tags | Alcohol; Physical Chemistry; Silicate; Catalysis; Dehydration | ||
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Abstract:
Dehydration of various butyl alcohols in the presence of silicate catalysts with widely ranging strengths of their acidic centers has been studied. Increasing basicity of the reactants or of the strength of acidic centers of catalysts increases the reaction rate. On protonic reaction centers, dehydration proceeds through the equilibrium formation of hydrogen-bonded complexes.
Исследована реакция дегидратации бутиловых спиртов различного строения в присутствии силикатных катализаторов, сила кислотных центров которых изменяется в широком диапазоне. Показано, что при увеличении основности реагента или силы кислотных центров катализаторов скорость реакции возрастает. На протонных центрах реакция дегидратации протекает через равновесный этап образования молекулярных водородносвязанных комплексов.
Cite:
Malysheva L.V.
, Kotsarenko N.S.
, Paukshtis E.A.
Influence of the Basicity of Butyl Alcohols on Their Reactivity
Reaction Kinetics and Catalysis Letters. 1981. V.16. N4. P.365-369. DOI: 10.1007/BF02066592 WOS Scopus РИНЦ
Influence of the Basicity of Butyl Alcohols on Their Reactivity
Reaction Kinetics and Catalysis Letters. 1981. V.16. N4. P.365-369. DOI: 10.1007/BF02066592 WOS Scopus РИНЦ
Dates:
Submitted: | Oct 16, 1980 |
Accepted: | Dec 19, 1980 |
Published print: | Jun 1, 1981 |
Identifiers:
Web of science | WOS:A1981MA22500013 |
Scopus | 2-s2.0-0037945163 |
Elibrary | 31107723 |
Chemical Abstracts | 1981:549589 |
Chemical Abstracts (print) | 95:149589 |
OpenAlex | W1969688652 |