1H, 13C and 17O NMR Studies of Cumene Hydroperoxide Coordination to Cr(AA)3 | Sciact - CRIS-system of Boreskov Institute of Catalysis

1H, 13C and 17O NMR Studies of Cumene Hydroperoxide Coordination to Cr(AA)3 Full article

Общее

Language: Английский, Genre: Full article,
Status: Published, Source type: Original

Journal

Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837

Output data

Year: 1985, Volume: 28, Number: 1, Pages: 145-152 Pages count : 8 DOI: 10.1007/BF02116771

Authors

Zimin Y.S.

¹ , Stepanov A.G.

¹ , Nekipelov V.M.

Affiliations

1	Institute of Catalysis, Novosibirsk, USSR

It has been established that the outer sphere coordination of cumene hydroperoxide to Cr(AA)3 is due to both the formation of hydrogen bonds between hydroxyl proton and chelate oxygen atoms and the π-π-interactions between the aromatic ring and chelate π-system. Установлено, что внешнесферная координация гидроперекиси кумола к трис-ацетилацетонату Cr(III) происходит как за счёт образования водородных связей гидроксильного протона с атомами кислорода хелата, так и за счёт π-π-взаимодействий ароматического кольца с π-системой хелата.

Zimin Y.S. , Stepanov A.G. , Nekipelov V.M.
1H, 13C and 17O NMR Studies of Cumene Hydroperoxide Coordination to Cr(AA)3
Reaction Kinetics and Catalysis Letters. 1985. V.28. N1. P.145-152. DOI: 10.1007/BF02116771 publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type

Submitted:	Apr 5, 1984
Accepted:	Jul 26, 1984
Published print:	Mar 1, 1985

publication_identifier.wos_identifier_type	WOS:A1985AQT0300022
publication_identifier.scopus_identifier_type	2-s2.0-34250118327
publication_identifier.rinz_identifier_type	30852805
publication_identifier.accession_number_identifier_type	1985:588455
publication_identifier.chemical_accession_number_identifier_type	103:188455