Decomposition of Alkanethiols to Dialkyl Sulfides and Hydrogen Sulfide Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
||||
---|---|---|---|---|---|
Output data | Year: 1990, Volume: 41, Number: 2, Pages: 357-362 Pages count : 6 DOI: 10.1007/BF02097894 | ||||
Tags | Hydrogen; Physical Chemistry; Sulfide; Catalysis; Dimethyl | ||||
Authors |
|
||||
Affiliations |
|
Abstract:
Disproportionation of thiol to sulfide and H2S takes place on catalysts of various composition, the most active being those with paired acid-base centers. On these catalysts at 200–400°C methanethiol is quantitatively converted to dimethyl sulfide. Disproportionation of ethanethiol and particularly of 2-propanethiol is accompanied by the decomposition of sulfides formed and initial thiols to produce olefins and H2S.
Cite:
Mashkina A.V.
, Grunvald V.R.
, Nasteka V.I.
, Borodin B.P.
, Yakovleva V.N.
, Khairulina L.N.
Decomposition of Alkanethiols to Dialkyl Sulfides and Hydrogen Sulfide
Reaction Kinetics and Catalysis Letters. 1990. V.41. N2. P.357-362. DOI: 10.1007/BF02097894 WOS Scopus РИНЦ
Decomposition of Alkanethiols to Dialkyl Sulfides and Hydrogen Sulfide
Reaction Kinetics and Catalysis Letters. 1990. V.41. N2. P.357-362. DOI: 10.1007/BF02097894 WOS Scopus РИНЦ
Dates:
Submitted: | Sep 14, 1989 |
Accepted: | Oct 12, 1989 |
Published print: | May 1, 1990 |
Identifiers:
Web of science | WOS:A1990DH52100021 |
Scopus | 2-s2.0-0006555852 |
Elibrary | 30801548 |
Chemical Abstracts | 1990:496892 |
Chemical Abstracts (print) | 113:96892 |
OpenAlex | W1972493496 |