Catalytic Decomposition of Dimethyl Disulfide Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 1994, Volume: 53, Number: 2, Pages: 363-368 Pages count : 6 DOI: 10.1007/BF02073043 | ||
Tags | Methyl; Physical Chemistry; Catalysis; Helium; Dimethyl | ||
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Abstract:
We have studied dimethyl disulfide conversion on heterogeneous catalysts in a flow setup at T=250–350°C and atmospheric pressure. Methyl mercaptan appears to be the main reaction product. The rate of dimethyl disulfide decomposition and its selectivity towards methyl mercaptan in H2S medium are higher than those in pure helium. Thus the process seems to involve the surface protons formed upon dissociative H2S chemisorption.
Cite:
Mashkina A.V.
, Yakovleva V.N.
, Sakhaltueva L.G.
Catalytic Decomposition of Dimethyl Disulfide
Reaction Kinetics and Catalysis Letters. 1994. V.53. N2. P.363-368. DOI: 10.1007/BF02073043 WOS Scopus РИНЦ
Catalytic Decomposition of Dimethyl Disulfide
Reaction Kinetics and Catalysis Letters. 1994. V.53. N2. P.363-368. DOI: 10.1007/BF02073043 WOS Scopus РИНЦ
Dates:
Submitted: | Apr 14, 1994 |
Accepted: | Jun 8, 1994 |
Published print: | Nov 1, 1994 |
Identifiers:
Web of science | WOS:A1994QQ99800017 |
Scopus | 2-s2.0-0028550644 |
Elibrary | 31157067 |
Chemical Abstracts | 1995:449915 |
Chemical Abstracts (print) | 122:198041 |
OpenAlex | W2026706549 |