1H NMR Study of the Mechanism of Ethyleneglycol Monoacetate Formation in Oxidative Acetoxylation of Ethylene Catalyzed by Pd(II) Complexes Full article
Conference |
New Developments in Selective Oxidation: International Symposium 18-22 Sep 1989 , Rimini |
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Source | New Developments in Selective Oxidation : Proceedings of an International Symposium, Rimini, Italy, September 18-22, 1989 Compilation, 1990. 891 c. ISBN 9780444886941. |
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Journal |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
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Output data | Year: 1990, Volume: 55, Pages: 213-220 Pages count : 8 DOI: 10.1016/S0167-2991(08)60151-2 | ||
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Abstract:
A detailed mechanism of ethylene oxidation by Pd(NOn)CIL2 complexes (n=2,3; L=CD3CN) in a chloroform-acetic acid nmixture is studied by 1H N M R spectroscopy. The end reaction products are ethyleneglycol monoacetate (EGMA), acetaldehyde, nitroethylene and compounds with the general formula CH3-CHXY (X, Y = OH, OAc, Cl, NO2), whose ratio depends upon the solvent composition. Kinetic and spectral data obtained indicate the formation of a number of intermediates. The structure and routes of decomposition of the intermediates to EGMA and other reaction products are suggested.
Cite:
Gusevskaya E.V.
, Beck I.E.
, Stepanov A.G.
, Likholobov V.A.
, Zamaraev K.I.
1H NMR Study of the Mechanism of Ethyleneglycol Monoacetate Formation in Oxidative Acetoxylation of Ethylene Catalyzed by Pd(II) Complexes
In compilation New Developments in Selective Oxidation : Proceedings of an International Symposium, Rimini, Italy, September 18-22, 1989. 1990. – C.213-220. – ISBN 9780444886941. DOI: 10.1016/S0167-2991(08)60151-2 WOS Scopus РИНЦ
1H NMR Study of the Mechanism of Ethyleneglycol Monoacetate Formation in Oxidative Acetoxylation of Ethylene Catalyzed by Pd(II) Complexes
In compilation New Developments in Selective Oxidation : Proceedings of an International Symposium, Rimini, Italy, September 18-22, 1989. 1990. – C.213-220. – ISBN 9780444886941. DOI: 10.1016/S0167-2991(08)60151-2 WOS Scopus РИНЦ
Dates:
Published print: | Jan 1, 1990 |
Published online: | Mar 4, 2008 |
Identifiers:
Web of science | WOS:A1990BQ92M00022 |
Scopus | 2-s2.0-77956928035 |
Elibrary | 30705829 |
Chemical Abstracts | 2010:1601960 |
Chemical Abstracts (print) | 156:420900 |
OpenAlex | W168797892 |