Direct Observation of Surface Mobility with Microscopic Techniques Photoemission Electron- and Field Electron Microscopy Full article
Conference |
New Aspects of Spillover Effect in Catalysis For Development of Highly Active Catalysts : Third International Conference on Spillover 17-20 Aug 1993 , Kyoto |
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Source | New Aspects of Spillover Effect in Catalysis For Development of Highly Active Catalysts : Proceedings of the Third International Conference on Spillover, 17-20 August 1993, Kyoto, Japan Compilation, Elsevier. Amsterdam.1993. 435 c. ISBN 9780444899644. |
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Journal |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
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Output data | Year: 1993, Volume: 77, Pages: 189-194 Pages count : 6 DOI: 10.1016/S0167-2991(08)63173-0 | ||||
Authors |
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Affiliations |
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Funding (3)
1 | German Research Foundation | SFB 6/81 |
2 | Max Planck Society | |
3 | Society for Chemical Engineering and Biotechnology |
Abstract:
Two new technical developments have been applied in order to investigate surface mobility in real time on the microscopic scale. The PEEM-technique (Photoemission Electron Microscopy) registers the local work function as induced by adsorption structures during catalytic reactions. The FEM-technique (Field Electron Microscopy) was also applied in situ during surface reactions. Both techniques are operated at low gas pressures, low emission currents and high detector amplification. Thus, gas phase ionization is omitted and still bright emission pattern are obtained.
Systems with bistable adsorption structures as well as those with oscillating reactions have been investigated. On Pt- and Pd-single crystal planes as well as on Pt-field emitter surfaces fundamental processes such as phase nucleation, reaction wave propagation and synchronization in surface reactions, could be studied during oscillatory behaviour of carbon monoxide oxidation. In a new attempt of spillover research the mobility and transfer of adsorbed particles across different surface structures (including subsurface oxides) has been investigated.
Cite:
Block J.H.
, Ehsasi M.
, Gorodetskii V.V.
, Karpowicz A.
, Berdau M.
Direct Observation of Surface Mobility with Microscopic Techniques Photoemission Electron- and Field Electron Microscopy
In compilation New Aspects of Spillover Effect in Catalysis For Development of Highly Active Catalysts : Proceedings of the Third International Conference on Spillover, 17-20 August 1993, Kyoto, Japan. – Elsevier., 1993. – C.189-194. – ISBN 9780444899644. DOI: 10.1016/S0167-2991(08)63173-0 WOS Scopus РИНЦ
Direct Observation of Surface Mobility with Microscopic Techniques Photoemission Electron- and Field Electron Microscopy
In compilation New Aspects of Spillover Effect in Catalysis For Development of Highly Active Catalysts : Proceedings of the Third International Conference on Spillover, 17-20 August 1993, Kyoto, Japan. – Elsevier., 1993. – C.189-194. – ISBN 9780444899644. DOI: 10.1016/S0167-2991(08)63173-0 WOS Scopus РИНЦ
Dates:
Published print: | Jan 1, 1993 |
Published online: | Apr 15, 2008 |
Identifiers:
Web of science | WOS:A1993MK94000026 |
Scopus | 2-s2.0-22344444396 |
Elibrary | 31114610 |
Chemical Abstracts | 1994:174601 |
Chemical Abstracts (print) | 120:174601 |
OpenAlex | W132417065 |