The Role of Various Modes of Adsorbed Carbon Monoxide in Synthesis Gas Conversion of Lanthanide Ions Promoted by Supported Palladium Catalysts Full article
Conference |
New Frontiers in Catalysis : 10th International Congress on Catalysis 19-24 Jul 1992 , Budapest |
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Source | New Frontiers in Catalysis : Proceedings of the 10th International Congress on Catalysis, Budapest, 19-24 July 1992 Compilation, Elsevier. Amsterdam-London-New York-Tokyo.1993. 2859 c. |
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Journal |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
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Output data | Year: 1993, Volume: 75, Pages: 2031-2034 Pages count : 4 DOI: 10.1016/S0167-2991(08)64218-4 | ||||
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Abstract:
Some dispersed supported metals (e.g., Pd or Rh) show catalytic activity in vapor-phase olefin hydroformylation. The reaction can be used for the study of migratory CO insertion as an elementary step in the alcohol formation and chain propagation in synthesis gas conversion. The modification of supported Rh by Fe(III) ions results in the enhancement of oxygenate formation in propylene hydroformylation. This fact has been accounted for by the promotion of migratory CO insertion due to its bi-site activation on surface bimetallic Rh–Fe3+ ensembles. To understand the role of CO adsorption mode in synthesis gas conversion on modified supported Pd catalysts, this chapter reviews propylene and hexene-1 hydroformylation on supported Pd + Ln and Pd catalysts. Some (Pd + Ln)/support catalysts having a low frequency mode of adsorbed CO show no activity in olefin hydroformylation. The level of catalytic activity of other catalysts is lower than that of unmodified Pd catalyst where the low frequency mode of adsorbed CO is not observed.
Cite:
Nogin Y.N.
, Chesnokov N.V.
, Kovalchuk V.I.
The Role of Various Modes of Adsorbed Carbon Monoxide in Synthesis Gas Conversion of Lanthanide Ions Promoted by Supported Palladium Catalysts
In compilation New Frontiers in Catalysis : Proceedings of the 10th International Congress on Catalysis, Budapest, 19-24 July 1992. – Elsevier., 1993. – Т.1-3. – C.2031-2034. DOI: 10.1016/S0167-2991(08)64218-4 WOS WOS Scopus РИНЦ
The Role of Various Modes of Adsorbed Carbon Monoxide in Synthesis Gas Conversion of Lanthanide Ions Promoted by Supported Palladium Catalysts
In compilation New Frontiers in Catalysis : Proceedings of the 10th International Congress on Catalysis, Budapest, 19-24 July 1992. – Elsevier., 1993. – Т.1-3. – C.2031-2034. DOI: 10.1016/S0167-2991(08)64218-4 WOS WOS Scopus РИНЦ
Dates:
Published print: | Jan 1, 1993 |
Published online: | Jul 24, 2008 |
Identifiers:
Web of science | WOS:A1993BZ35K00034 , WOS:A1993MK93400034 |
Scopus | 2-s2.0-77956945358 |
Elibrary | 30730052 |
Chemical Abstracts | 1993:673828 |
Chemical Abstracts (print) | 119:273828 |
OpenAlex | W1832778783 |