Supported Metal Complexes as Hydrogenation Catalysts Full article
Source | Catalytic Hydrogenation Compilation, Elsevier B.V.. 1986. 677 c. ISBN 978-0-444-42682-6. |
||
---|---|---|---|
Journal |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
||
Output data | Year: 1986, Volume: 27, Pages: 459-495 Pages count : 37 DOI: 10.1016/S0167-2991(08)65359-8 | ||
Authors |
|
||
Affiliations |
|
Abstract:
This chapter discusses the use of supported metal complexes as hydrogenation catalysts. The anchoring of metal complexes on support surfaces began a novel trend in catalyst preparation. The application of metal complexes on support surfaces enables a wide variation of the composition of the active centers because the choice of ligands is not restricted by the solubility of the metal compound. Several types of hydrogenation catalysts may be prepared via the anchoring of metal complexes on supports: (1) heterogenized metal complexes, (2) complexes attached to surface ligands, (3) surface coordinatively unsaturated metal ions or hydrides, and (4) super-dispersed supported mono- and polynuclear catalysts. The chapter considers their use in only one reaction—the catalytic hydrogenation of unsaturated compounds. Results in the hydrogenation of CO, isomerization, metathesis, hydroxylation, hydroformylation, carbonylation, oligomerization, polymerization, and other reactions have also been obtained.
Cite:
Yermakov Y.I.
, Arzamaskova L.N.
Supported Metal Complexes as Hydrogenation Catalysts
In compilation Catalytic Hydrogenation. – Elsevier B.V.., 1986. – C.459-495. – ISBN 978-0-444-42682-6. DOI: 10.1016/S0167-2991(08)65359-8 Scopus РИНЦ
Supported Metal Complexes as Hydrogenation Catalysts
In compilation Catalytic Hydrogenation. – Elsevier B.V.., 1986. – C.459-495. – ISBN 978-0-444-42682-6. DOI: 10.1016/S0167-2991(08)65359-8 Scopus РИНЦ
Dates:
Published print: | Jan 1, 1986 |
Published online: | Jan 4, 2009 |
Identifiers:
Scopus | 2-s2.0-77956961617 |
Elibrary | 30927463 |
Chemical Abstracts | 1986:632995 |
Chemical Abstracts (print) | 105:232995 |
OpenAlex | W1609358588 |