The Catalytic Activity of Nickel in Type-Y Zeolite Catalysts for the Hydrogenation of Unsaturated Hydrocarbons Full article
Journal |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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Output data | Year: 1979, Volume: 28, Number: 1, Pages: 7-12 Pages count : 6 DOI: 10.1007/BF00925387 | ||
Tags | Oxygen; Hydrogenation; Nickel; Benzene; Zeolite | ||
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Abstract:
Conclusions:
1. It has been shown that there is no correlation between the surface area of the nickel active in the hydrogenation of olefins on nickel-containing zeolites and the surface area determined from the chemisorption of oxygen. This lack of correlation is due to the fact that the reduction of Ni(II) is reversible, the equilibrium point being shifted toward Ni(II) in oxygen, inert gases, and benzene, and toward Ni(0) in olefins.
2. Nickel clusters embedded in the zeolite cavities are incapable of catalyzing the hydrogenation of benzene, the equilibrium point in the reduction of nickel cations being shifted toward the Ni(II) side.
Cite:
Romannikov V.N.
, Ione K.G.
, Repina V.V.
The Catalytic Activity of Nickel in Type-Y Zeolite Catalysts for the Hydrogenation of Unsaturated Hydrocarbons
Russian Chemical Bulletin. 1979. V.28. N1. P.7-12. DOI: 10.1007/BF00925387 WOS Scopus РИНЦ
The Catalytic Activity of Nickel in Type-Y Zeolite Catalysts for the Hydrogenation of Unsaturated Hydrocarbons
Russian Chemical Bulletin. 1979. V.28. N1. P.7-12. DOI: 10.1007/BF00925387 WOS Scopus РИНЦ
Original:
Романников В.Н.
, Ионе К.Г.
, Репина В.В.
Каталитические свойства никеля в цеолитах типа Y в реакции гидрирования ненасыщенных углеводородов
Известия Академии наук. Серия химическая. 1979. №1. С.13-19. РИНЦ
Каталитические свойства никеля в цеолитах типа Y в реакции гидрирования ненасыщенных углеводородов
Известия Академии наук. Серия химическая. 1979. №1. С.13-19. РИНЦ
Dates:
Submitted: | Jul 28, 1977 |
Published print: | Jan 1, 1979 |
Identifiers:
Web of science | WOS:A1979HM71800002 |
Scopus | 2-s2.0-34250265708 |
Elibrary | 30921974 |
OpenAlex | W2016980489 |