Transformations of Hydrocarbons on Zeolites of Type Y: III. Hydrogenation of Unsaturated Hydrocarbons on Pd-, Pt-, and Ru-Containing Zeolites Full article
Journal |
Journal of Catalysis
ISSN: 0021-9517 , E-ISSN: 1090-2694 |
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Output data | Year: 1980, Volume: 66, Number: 1, Pages: 121-129 Pages count : 9 DOI: 10.1016/0021-9517(80)90014-7 | ||||
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Abstract:
On the basis of IR and XPS data, measurements of magnetic susceptibility, and investigation of hydrogenation reaction rates of some unsaturated hydrocarbons, it has been established that electronic state and catalytic properties of the metal stabilized inside zeolite cavities are determined by the equilibrium position of interaction in the “reagent-metal-carrier” system. Position of this equilibrium depends on both electron-acceptive properties of the carrier surface and electron-donative properties of reagent molecules. It has been shown that the ratio of reaction rates of hydrogenation of hydrocarbons of different nature (factor of selectivity) is determined by the position of above-mentioned equilibrium too.
Cite:
Romannikov V.N.
, Ione K.G.
, Pedersen L.A.
Transformations of Hydrocarbons on Zeolites of Type Y: III. Hydrogenation of Unsaturated Hydrocarbons on Pd-, Pt-, and Ru-Containing Zeolites
Journal of Catalysis. 1980. V.66. N1. P.121-129. DOI: 10.1016/0021-9517(80)90014-7 WOS Scopus РИНЦ
Transformations of Hydrocarbons on Zeolites of Type Y: III. Hydrogenation of Unsaturated Hydrocarbons on Pd-, Pt-, and Ru-Containing Zeolites
Journal of Catalysis. 1980. V.66. N1. P.121-129. DOI: 10.1016/0021-9517(80)90014-7 WOS Scopus РИНЦ
Dates:
Submitted: | Jul 6, 1979 |
Accepted: | Apr 15, 1980 |
Published print: | Nov 1, 1980 |
Published online: | May 24, 2004 |
Identifiers:
Web of science | WOS:A1980KP93400013 |
Scopus | 2-s2.0-0000076627 |
Elibrary | 30055831 |
Chemical Abstracts | 1981:17984 |
Chemical Abstracts (print) | 94:17984 |
OpenAlex | W2022851874 |