The Surface Compounds and the Routes of Formation of the Reaction Products in the Interaction of Propylene with Zinc Oxide Full article
Journal |
Journal of Catalysis
ISSN: 0021-9517 , E-ISSN: 1090-2694 |
||
---|---|---|---|
Output data | Year: 1979, Volume: 58, Number: 1, Pages: 1-7 Pages count : 7 DOI: 10.1016/0021-9517(79)90236-7 | ||
Authors |
|
||
Affiliations |
|
Abstract:
Thermodesorption of propylene, acrolein, allyl bromide, and their conversion products on zinc oxide has been investigated. Infrared spectra of allyl bromide have been studied. On the basis of the results obtained and the literature data a scheme of propylene transformation on zinc oxide has been proposed which explains the presence of dimerization products and the absence of acrolein in the reaction products by difficulty of transformation of an allylic compound to a cationic form on this catalyst. The interaction of allyl bromide, forming an allyl cation, with zinc oxide leads to evolution of acrolein.
Cite:
Davydov A.A.
, Yefremov A.A.
, Mikhalchenko V.G.
, Sokolovskii V.D.
The Surface Compounds and the Routes of Formation of the Reaction Products in the Interaction of Propylene with Zinc Oxide
Journal of Catalysis. 1979. V.58. N1. P.1-7. DOI: 10.1016/0021-9517(79)90236-7 WOS Scopus РИНЦ
The Surface Compounds and the Routes of Formation of the Reaction Products in the Interaction of Propylene with Zinc Oxide
Journal of Catalysis. 1979. V.58. N1. P.1-7. DOI: 10.1016/0021-9517(79)90236-7 WOS Scopus РИНЦ
Dates:
Submitted: | Apr 19, 1978 |
Accepted: | Nov 6, 1978 |
Published print: | Jun 15, 1979 |
Published online: | May 24, 2004 |
Identifiers:
Web of science | WOS:A1979GW45800001 |
Scopus | 2-s2.0-4243129772 |
Elibrary | 30895849 |
Chemical Abstracts | 1979:456243 |
Chemical Abstracts (print) | 91:56243 |
OpenAlex | W1999990368 |