Liquid-Phase Oxidation of Alkyl Sulfides Catalyzed by a Heteropoly Acid Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 1979, Volume: 20, Number: 2, Pages: 416-419 Pages count : 4 | ||
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Abstract:
H3+nPMo12-nVnO40 (n = 1-6) catalyzed the oxidation of R2S (R = Me, Et, Bu) to R2SO and R2SO2 at 100-50°/9-80 atm in Me2CO, AcOH, or Me2CHOH with conversions and selectivities ≤100%. The catalyst activity was independent of concentration in the range 0.005-0.005 mol/L and decreased in the order n = 3 ≃2 >1 >6. A stepwise nonradical mechanism was proposed.
Cite:
Kozhevnikov I.V.
, Simagina V.I.
, Varnakova G.V.
, Matveev K.I.
Liquid-Phase Oxidation of Alkyl Sulfides Catalyzed by a Heteropoly Acid
Kinetics and Catalysis. 1979. V.20. N2. P.416-419. WOS РИНЦ
Liquid-Phase Oxidation of Alkyl Sulfides Catalyzed by a Heteropoly Acid
Kinetics and Catalysis. 1979. V.20. N2. P.416-419. WOS РИНЦ
Original:
Кожевников И.В.
, Симагина В.И.
, Варнакова Г.В.
, Матвеев К.И.
Жидкофазное окисление алкилсульфидов, катализированное гетерополикислотой
Кинетика и катализ. 1979. Т.20. №2. С.506-510. РИНЦ
Жидкофазное окисление алкилсульфидов, катализированное гетерополикислотой
Кинетика и катализ. 1979. Т.20. №2. С.506-510. РИНЦ
Identifiers:
Web of science | WOS:A1979HV72400021 |
Elibrary | 29310196 |