Telomerization of Butadiene with Diethylamine Catalyzed by Ni, Pd and Pt Allyl Halide Complexes Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 1978, Volume: 8, Number: 2, Pages: 263-268 Pages count : 6 DOI: 10.1007/BF02061315 | ||
Tags | Physical Chemistry; Catalysis; Halide; PPh3; Allyl | ||
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Abstract:
The telomerization of butadiene with diethylamine with the formation of the tertiary amine (C2H5)2NC8H13 is catalyzed by Ni, Pd and Pt allyl halide complexes. Triphenylphosphine increases the activity of such catalysts. The rate of telomerization depends strongly on the [PPh3]/[M] ratio (M=Pd and Pt) and increases in the series of metals: Ni<Pt<Pd. The activity of (π-C3H5PdCl)2 exceeds that of (π-C3H5)2 Pd by more than two orders of magnitude.
Cite:
Lazutkin A.M.
, Lazutkina A.I.
Telomerization of Butadiene with Diethylamine Catalyzed by Ni, Pd and Pt Allyl Halide Complexes
Reaction Kinetics and Catalysis Letters. 1978. V.8. N2. P.263-268. DOI: 10.1007/BF02061315 WOS Scopus РИНЦ
Telomerization of Butadiene with Diethylamine Catalyzed by Ni, Pd and Pt Allyl Halide Complexes
Reaction Kinetics and Catalysis Letters. 1978. V.8. N2. P.263-268. DOI: 10.1007/BF02061315 WOS Scopus РИНЦ
Dates:
Submitted: | Jun 15, 1977 |
Accepted: | Oct 25, 1977 |
Published print: | Mar 1, 1978 |
Identifiers:
Web of science | WOS:A1978FE11300021 |
Scopus | 2-s2.0-34250277545 |
Elibrary | 30905375 |
Chemical Abstracts | 1978:529006 |
Chemical Abstracts (print) | 89:129006 |
OpenAlex | W2022335793 |