Catalytic Properties of Palladium Complexes with Silica-Anchored Phosphine Ligands in Vinyl Exchange Reaction
Full article
Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736
, E-ISSN: 1588-2837
|
Output data |
Year: 1979,
Volume: 12,
Number: 2,
Pages: 177-181
Pages count
: 5
DOI:
10.1007/BF02071907
|
Authors |
Chistyakov S.I.
1
,
Semikolenov V.A.
1
,
Likholobov V.A.
1
,
Yermakov Yu.I.
1
|
Affiliations |
1 |
Institute of Catalysis, Novosibirsk, USSR
|
|
Catalytic properties of Pd complexes with phosphine ligands anchored to silica have been studied. The valence state of Pd and the acidity of the alcohol were found to influence the rate of vinyl exchange. A possible reaction mechanism is proposed.