Calculation of the Ultraviolet and Visible Spectra of Copper Acetylacetonate Full article
Journal |
Theoretical and Experimental Chemistry
ISSN: 0040-5760 , E-ISSN: 1573-935X |
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Output data | Year: 1966, Volume: 2, Number: 5, Pages: 451-455 Pages count : 5 DOI: 10.1007/BF01111986 | ||
Tags | Copper; Absorption Band; Charge Transfer; Visible Region; Oscillator Strength | ||
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Abstract:
The calculation of the acetylacetonate complex of copper was performed by the Wolfsberg-Helmholz method. An interpretation of the observed absorption bands in the ultraviolet (UV) and visible regions is given. It is shown that the bands at 200, 250, and 390 mμ belong to spectra with a charge transfer of the ligand-metal type; the 300 mμ band belongs to interligand transition of the π→π* type; the 560 and 670 mμ bands are associated with d-d transitions. The effective charges at the atoms and, for some transitions, the oscillator strengths, are calculated.
Cite:
Avdeev V.I.
, Zakharov I.I.
Calculation of the Ultraviolet and Visible Spectra of Copper Acetylacetonate
Theoretical and Experimental Chemistry. 1966. V.2. N5. P.451-455. DOI: 10.1007/BF01111986 Scopus РИНЦ
Calculation of the Ultraviolet and Visible Spectra of Copper Acetylacetonate
Theoretical and Experimental Chemistry. 1966. V.2. N5. P.451-455. DOI: 10.1007/BF01111986 Scopus РИНЦ
Original:
Авдеев В.И.
, Захаров И.И.
Расчет ультрафиолетового и видимого спектров ацетилацетоната меди
Теоретическая и экспериментальная химия. 1966. Т.2. №5. С.609-615. РИНЦ
Расчет ультрафиолетового и видимого спектров ацетилацетоната меди
Теоретическая и экспериментальная химия. 1966. Т.2. №5. С.609-615. РИНЦ
Dates:
Submitted: | Jan 14, 1966 |
Published print: | Sep 1, 1966 |
Identifiers:
Scopus | 2-s2.0-34250539251 |
Elibrary | 30649558 |
OpenAlex | W2036304552 |