Simulation of the Charge and Potential Distribution in the Double Layer Formed by Polymer Electrolyte Full article
Journal |
Electrochemistry Communications
ISSN: 1388-2481 |
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Output data | Year: 2006, Volume: 8, Number: 4, Pages: 561-564 Pages count : 4 DOI: 10.1016/j.elecom.2006.01.027 | ||||
Tags | Computer simulations, Electrochemistry, Low-temperature hydrogen-oxygen fuel cells, Models of surface chemical reactions | ||||
Authors |
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Affiliations |
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Funding (2)
1 | New Energy and Industrial Technology Development Organization | 95014 |
2 | Chalmers University of Technology |
Abstract:
We present Monte Carlo simulations of phase separation on the nm scale in the double layer formed by wetted NAFION or NAFION-type polymer electrolyte near the charged metal surface. The results obtained indicate that the phase separation may cause appreciable spatial fluctuations of the potential near the surface. If e.g. the drop of the potential in the double layer is about 1 V, the amplitude of the fluctuations of the potential may be 0.2–0.3 V. Such fluctuations may influence the rate of electrochemical reactions.
Cite:
Zhdanov V.P.
, Kasemo B.
Simulation of the Charge and Potential Distribution in the Double Layer Formed by Polymer Electrolyte
Electrochemistry Communications. 2006. V.8. N4. P.561-564. DOI: 10.1016/j.elecom.2006.01.027 WOS Scopus РИНЦ
Simulation of the Charge and Potential Distribution in the Double Layer Formed by Polymer Electrolyte
Electrochemistry Communications. 2006. V.8. N4. P.561-564. DOI: 10.1016/j.elecom.2006.01.027 WOS Scopus РИНЦ
Dates:
Submitted: | Jan 16, 2006 |
Accepted: | Jan 30, 2006 |
Published online: | Feb 28, 2006 |
Published print: | Apr 1, 2006 |
Identifiers:
Web of science | WOS:000236696300010 |
Scopus | 2-s2.0-33645232194 |
Elibrary | 13518706 |
Chemical Abstracts | 2006:310718 |
Chemical Abstracts (print) | 145:197510 |
OpenAlex | W1969275969 |