Catalytic Oxidation of Organic Compounds with Oxygen in the Presence of Mo–V–Phosphoric Heteropoly Acid Solutions Review
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 2008, Volume: 49, Number: 6, Pages: 773-781 Pages count : 9 DOI: 10.1134/S0023158408060025 | ||
Tags | Anthraquinone; Catalytic Oxidation; Methyl Ethyl Ketone; Methyl Ethyl Ketone; Heteropoly Acid | ||
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Affiliations |
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Abstract:
The studies carried out at the Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, on the selective catalytic oxidation of organic compounds with oxygen in the presence of aqueous solutions of Mo-V-phosphoric heteropoly acids (HPAs) are reviewed. Alkylphenols are oxidized into 1,4-quinones with a selectivity of 85–99%, and C2-C4 olefins in the presence of Pd complexes are oxidized into carbonyl compounds with a selectivity of 98–99%. The bifunctional (acidic and oxidizing) properties of HPA solutions were used for the first time to synthesize anthraquinones and vitamin K3.
Cite:
Zhizhina E.G.
, Odyakov V.F.
, Simonova M.V.
Catalytic Oxidation of Organic Compounds with Oxygen in the Presence of Mo–V–Phosphoric Heteropoly Acid Solutions
Kinetics and Catalysis. 2008. V.49. N6. P.773-781. DOI: 10.1134/S0023158408060025 WOS Scopus РИНЦ
Catalytic Oxidation of Organic Compounds with Oxygen in the Presence of Mo–V–Phosphoric Heteropoly Acid Solutions
Kinetics and Catalysis. 2008. V.49. N6. P.773-781. DOI: 10.1134/S0023158408060025 WOS Scopus РИНЦ
Original:
Жижина Е.Г.
, Одяков В.Ф.
, Симонова М.В.
Каталитические процессы окисления органических соединений кислородом в присутствии растворов Mo-V-фосфорных гетерополикислот
Кинетика и катализ. 2008. Т.49. №6. С.814-823. РИНЦ
Каталитические процессы окисления органических соединений кислородом в присутствии растворов Mo-V-фосфорных гетерополикислот
Кинетика и катализ. 2008. Т.49. №6. С.814-823. РИНЦ
Dates:
Submitted: | Feb 27, 2008 |
Published print: | Nov 1, 2008 |
Published online: | Dec 3, 2008 |
Identifiers:
Web of science | WOS:000261342700002 |
Scopus | 2-s2.0-57449100043 |
Elibrary | 13586364 |
Chemical Abstracts | 2008:1443228 |
Chemical Abstracts (print) | 151:316157 |
OpenAlex | W2011286334 |