103Rh, 17O, and 31P NMR Study of Rh(III) Complex Formation in Acidic Sulfate-Phosphate Media
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Translated
|
| Journal |
Russian Journal of Inorganic Chemistry
ISSN: 0036-0236
, E-ISSN: 1531-8613
|
| Output data |
Year: 2012,
Volume: 57,
Number: 2,
Pages: 231-236
Pages count
: 6
DOI:
10.1134/S0036023612020040
|
| Authors |
Belyaev A.V.
1
,
Vorobʹeva S.N.
2
,
Fedotov M.A.
2
|
| Affiliations |
| 1 |
Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
|
| 2 |
Boreskov Institute of Catalysis, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090 Russia
|
|
Rhodium(III) complex formation with phosphoric acid in strong acidic solutions has been studied by 103Rh, 17O, and 31P NMR. Phosphoric acid is mainly coordinated to rhodium as a monodentate terminal HPO 4 2− ion, while the coordinated phosphate ion accounts for no more than 7%.