Catalysis by Heteropoly Acids and Multicomponent Polyoxometalates in Liquid-Phase Reactions
Review
| Общее |
Language:
Английский,
Genre:
Review,
Status:
Published,
Source type:
Original
|
| Journal |
Chemical Reviews
ISSN: 0009-2665
, E-ISSN: 1520-6890
|
| Output data |
Year: 1998,
Volume: 98,
Number: 1,
Pages: 171-198
Pages count
: 29
DOI:
10.1021/CR960400Y
|
| Authors |
Kozhevnikov I.V.
1
|
| Affiliations |
| 1 |
Leverhulme Centre for Innovative Catalysis, Department of Chemistry, The University of Liverpool, Liverpool L69 7ZD, UK
|
|
A review with 275 refs. on topics of: I. Acid Catalysis by Heteropoly Acids: A. HPA Catalysts: 1. Structure, 2. acid properties, 3. supported HPAs, 4. salts of HPAs; B. Homogenous Reactions: 1. Hydration of Olefins, 2. esterification and related reactions, 3. condensation, 4. misc. reactions; C. Biphasic Reactions: 1. Polymn. of THF, 2. esterification, 3. other reactions; D. Heterogeneously Catalyzed Liq.-Phase Reactions: 1. Paraffin alkylation, 2. Friedel-Crafts and related reactions, 3. esterification, hydrolysis and other related reactions, 4. misc. reactions; II. Multicomponent Polyoxometalates in Liq.-Phase Oxidn.: A. Oxidn. with Dioxygen: 1. General principles, 2. homogeneous oxidn., 3. biphasic oxidn., 4. heterogeneously catalyzed oxidn., 5. mechanism; B. Oxidn. with Hydrogen Peroxide: 1. Venturello-Ishii system, 2. other polyoxometalate systems.