Design of Ceramometal Cu-Al Catalyst with Egg-Shell Microstructure for Water-Gas Shift Reaction
Conference Abstracts
Общее |
Language:
Английский,
Genre:
Conference Abstracts,
Status:
Published,
Source type:
Original
|
Conference |
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 Aug - 4 Sep 2015
,
Казань
|
Source |
EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts
Compilation,
Boreskov Institute of Catalysis. Novosibirsk.2015.
2184 c. ISBN 9785906376107.
publication_identifier_short.rinz_identifier_type
|
Output data |
Year: 2015,
Pages: 485-486
Pages count
: 2
|
Authors |
Tikhov S.
1
,
Minyukova T.
1
,
Valeev K.
1
,
Cherepanova S.
1
,
Salanov A.
1
,
Kaichev V.
1
,
Saraev A.
1
,
Andreev A.
1
,
Lapina O.
1
,
Sadykov V.
1,2
,
Gerasimov K.
3
|
Affiliations |
1 |
Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
|
2 |
Novosibirsk State University, Novosibirsk, Russia
|
3 |
Institute of Solid State Chemistry and Mechanochemistry SB RAS, Novosibirsk, Russia
|
|
Funding (2)
1
|
European Commission
|
604296 FP7-NMP-2013-LARGE-7 BIOGO
|
2
|
Russian Foundation for Basic Research
|
14-08-00251
|
Water-gas shift reaction (WGS) is one of the primary industrial reactions of hydrogen production. One of the main problem of low temperature shift is the low activity of conventional catalyst per volume of the catalyst bed. The possible way to increase the volume activity is the use of ceramometal catalysts with enhanced real and loading density. In the presented work a new CuAl-based catalyst prepared through the stage of mechanical alloying of Cu-Al powders was developed. The detailed study of the structural, textural, surface and other physical properties in comparison with catalytic properties of cermet CuAlO/CuAl catalysts has been carried out. It was found that TOF values of some cermet catalyst are higher than for conventional CuZnAl oxide catalyst. The structure sensitivity of cermets has been discussed