Investigation of the Catalytic Oligomerization of Butadiene in the Presence of π-allyl Complexes of Platinum Full article
Conference |
5th International Congress on Catalysis 20-26 Aug 1972 , Miami Beach |
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Source | Catalysis: Proceedings of the Fifth International Congress on Catalysis, Miami Beach, USA, 20-26 August, 1972 Compilation, North-Holland Pub. Co. Amsterdam.1973. 1483 c. ISBN 9780720402711. РИНЦ |
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Output data | Year: 1973, Volume: 1, Pages: 409-419 Pages count : 11 | ||
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Abstract:
Oligomerization of butadiene [106-99-0], examd. in the presence of the π-allyl complexes of Pt, indicated the formation of low mol. wt. polymers due to an active monoallyl complex being formed, and of trimers and tetramers due to conversion of diallylplatinum halides to bis(π-allyl)platinum (I), and the conversion tendency decreased through the series Cl, Br, and I, in accordance with Pt-halogen bond stability. Diallylplatinum halides, (C3H5)2PtX(II; X = Cl, Br, I), prepd. quant. from I and allyl chloride, allyl bromide , and allyl iodide, and converted by dissoln. in halogenated solvents to monoallylplatinum halides, C3H5PtX were examd. by ir, NMR, and x-ray spectroscopy. The spectral anal. confirmed the π-nature of Pt-allyl group bond, indicated the similarity in electronic structures of Cl and Br which differed significantly from that of iodine, and suggested the electron acceptor property of the allyl group, and the assocn. of II complexes in soln.
Cite:
Lazutkin A.M.
, Lazutkina A.I.
, Ovsyannikova I.A.
, Yurtchenko E.N.
, Mastikhin V.M.
Investigation of the Catalytic Oligomerization of Butadiene in the Presence of π-allyl Complexes of Platinum
In compilation Catalysis: Proceedings of the Fifth International Congress on Catalysis, Miami Beach, USA, 20-26 August, 1972. – North-Holland Pub. Co., 1973. – C.409-419. – ISBN 9780720402711. РИНЦ
Investigation of the Catalytic Oligomerization of Butadiene in the Presence of π-allyl Complexes of Platinum
In compilation Catalysis: Proceedings of the Fifth International Congress on Catalysis, Miami Beach, USA, 20-26 August, 1972. – North-Holland Pub. Co., 1973. – C.409-419. – ISBN 9780720402711. РИНЦ
Identifiers:
Elibrary | 46571519 |
Chemical Abstracts | 1974:464894 |
Chemical Abstracts (print) | 81:64894 |
Citing:
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