Synthesis of New Chiral Schiff Bases from (+)-3-Carene and Their Use in Asymmetric Oxidation of Sulfides Catalyzed by Metal Complexes
Full article
| Общее |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Translated
|
| Journal |
Russian Journal of Organic Chemistry
ISSN: 1070-4280
, E-ISSN: 1608-3393
|
| Output data |
Year: 2009,
Volume: 45,
Number: 6,
Pages: 815-824
Pages count
: 10
DOI:
10.1134/S1070428009060037
|
| Authors |
Koneva E.A.
1
,
Volcho K.P.
1
,
Korchagina D.V.
1
,
Salakhutdinov N.F.
1
,
Tolstikov A.G.
2
|
| Affiliations |
| 1 |
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090 Russia
|
| 2 |
Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia
|
|
Funding (1)
|
1
|
Russian Foundation for Basic Research
|
06-03-32052
|
A number of new chiral Schiff bases were synthesized starting from accessible monoterpene (+)-3-carene, and the products were used as ligands in metal complex-catalyzed oxidation of sulfides to chiral sulfoxides. The optical purity and the sign of optical rotation of chiral sulfoxides were found to strongly depend on the oxidation temperature.